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11.
为建立和完善现代化的海洋灾害防治体系,提高我国海洋治理和应对全球气候变化的能力,文章以全球治理和国家治理为背景,在明确致灾因子、承灾体、灾害以及灾害风险和管理等基本概念及其内涵的基础上,分析全球气候变化背景下我国海洋灾害及其风险的特征以及海洋灾害防治的关键性和基础性科学问题,并提出我国构建海洋灾害防治体系的建议。研究结果表明:在全球气候变化的影响下,我国沿海地区的海洋灾害风险复杂多变且有所提升;提出以群-环-域为主体的体系架构,研究全球气候变化与区域海洋的响应和反馈、全球气候变化背景下海洋灾害与风险的特征和规律以及综合海洋灾害风险评估和海洋灾害防治等问题;在我国构建海洋灾害防治体系的过程中,应加强科学研究以及技术和信息支撑、促进区域和全球联动联防以及提高全社会对海洋灾害的认知和防范水平。  相似文献   
12.
混合岩型铀矿是康滇地轴上最有希望取得找矿突破的铀矿类型,海塔地区的铀矿化即是该类型铀矿的典型代表。本文针对区内的长英质脉矿石、富晶质铀矿石英脉矿石和含矿热液石英脉中的石英流体包裹体进行了研究。结果表明,海塔地区混合岩型铀矿的成矿作用可分为2个阶段:早期混合岩化热液成矿阶段为高温、中低盐度流体,流体包裹体均一温度集中在380~540℃,盐度变化范围为16.15%~23.18%NaCl eqv,是区内铀成矿的主要阶段;晚期热液叠加改造成矿阶段为中低温、低盐度流体,流体包裹体均一温度集中在140~220℃,盐度变化范围为5.56%~23.18%NaCleqv,是区内富铀矿的形成阶段。流体包裹体的气相成分测试表明,长英质脉矿石石英包裹体中以CH4、CO2为主,其次为H2O和N2;而富晶质铀矿石英脉及含矿热液石英脉石英包裹体中以H2为主,部分含有CO2、CH4、H2O。氢、氧同位素研究表明,早期混合岩化成矿阶段的成矿流体可能为岩浆水与变质水的混合,而晚期热液叠加改造成矿阶段成矿流体中可能有大气降水的加入。  相似文献   
13.
The lithium-rich brine in salt lakes is the main raw material of the world’s lithium products, while the continental geothermal fluids with a high salinity often contain a high concentration of lithium. Continental geothermal system is the focus in the study of geothermal formation mechanism. However, less attention is paid to the system due to the complexity of lithology, and the application of lithium isotopes in this field has not been systematically recognized. The newest application and progress of lithium isotope geochemistry in continental geothermal research in recent years were discussed, the problems in this field were put forward, and future research methods and directions were expected. The study of continental geothermal fluids should attach great importance to the application of Li-B-Sr-U multi-isotopic method, and should also be combined with water-rock reaction experiments under different temperature conditions. Moreover, in the future, the research on continental geothermal system should pay more attention to the various sediment/rock lithium isotopic compositions and their spatio-temporal distribution characteristics in the regional or geothermal field’s scales, mineralogy of reservoir rock, and behaviors of lithium isotopes related to the formation of secondary minerals in the process of water-rock interaction, in order to reveal the complex process of fluid evolution in the geothermal system and provide scientific reference for the exploration, exploitation and utilization of lithium resources in the system.  相似文献   
14.
Stable water isotopes δ18O and δ2H are used to investigate precipitation trends and storm dynamics to advance knowledge of precipitation patterns in a warming world. Herein, δ18O and δ2H were used to determine the relationship between extratropical cyclonic precipitation and local meteoric water lines (LMWLs) in the eastern Ohio Valley and the eastern United States. Precipitation volume weighted and unweighted central Ohio LMWLs, created with samples collected during 2012–2018, showed that temperature had the greatest effect on precipitation isotopic composition. HYSPLIT back trajectory modelling showed that precipitation was primarily derived from a mid-continental moisture source. Remnants of major hurricanes were collected as extratropical precipitation during the 2012–2018 sampling period in central Ohio. Extratropical precipitation samples were not significantly different from the samples that created the central Ohio LMWL. Six additional LMWLs were derived from United States Geological Survey (USGS) Atmospheric Integrated Research Monitoring Network (AIRMoN) samples collected in Pennsylvania, Delaware, Tennessee, Vermont, New Hampshire, and Oxford, Ohio. Meteoric water lines describing published samples from Superstorm Sandy, plotted with these AIRMoN LMWLs, showed isotopic composition of Superstorm Sandy precipitation was commonly more depleted than the average isotopic composition at the mid-latitude locations. Meteoric water lines describing the Superstorm Sandy precipitation were not significantly different in slope from LMWLs generated within 300 km of the USGS AIRMoN site. This finding, which was observed across the eastern Ohio Valley and eastern United States, demonstrated a consistent precipitation δ2H–δ18O relationship for extratropical cyclonic and non-cyclonic events. This work also facilitates the analysis of storm development based on the relationship between extratropical event signature and the LMWL. Analysis of extratropical precipitation in relation to LMWLs along storm tracks allows for stronger development of precipitation models and understanding of which climatic and atmospheric factors determine the isotopic composition of precipitation.  相似文献   
15.
The accurate and precise determination of Li isotopic composition by MC‐ICP‐MS suffers from the poor performance of traditional column chromatography. Previously established chromatographic processes cannot completely remove Na in complex geological samples, which is currently interpreted to be a result of Na breakthrough. In this study, Na breakthrough during single‐column purification was found to differ between simply artificial Na‐containing sample solutions, where a little Na residue was found, and silicate rocks, where a large amount of breakthrough occurred. A revised two‐step column purification for Li using 0.5 and 0.3 mol l?1 HCl as eluents was designed to remove the Na. This modified method achieves high‐efficiency Li purification from Na and consequently avoiding high Na/Li ratio interference for subsequent MC‐ICP‐MS analyses. The proposed method was validated by the analysis of a series of reference materials, including Li2CO3 (IRMM‐016, ‐0.10‰), basalt (BCR‐2: 2.68‰; BHVO‐2: 4.39‰), andesite (AGV‐2: 6.46‰; RGM‐2: 2.59‰), granodiorite (GSP‐2: ?0.87‰) and seawater (CASS‐5, 30.88‰). This work reports early Na appearance prior to the elution curves in chromatography and emphasises its influence for subsequent Li isotope measurement. Based on the findings, the established two‐step method would be more secure than single‐column chemistry for Li purification.  相似文献   
16.
《地学前缘(英文版)》2020,11(3):925-942
The Pb isotope composition of the upper mantle beneath Central Europe is heterogeneous due to the subduction of regionally contrasting material during the Variscan and Alpine orogenies.Late Variscan to Cenozoic mantlederived melts allow mapping this heterogeneity on a regional scale for the last ca.340 Myr.Late Cretaceous and Cenozoic anorogenic magmatic rocks of the Bohemian Massif(lamprophyres,volcanic rocks of basanite/tephrite and trachyte/phonolite series) concentrate mostly in the Eger Rift.Cretaceous ultramafic lamprophyres yielded the most radiogenic Pb isotope signatures reflecting a maximum contribution from metasomatised lithospheric mantle,whereas Tertiary alkaline lamprophyres originated from mantle with less radiogenic ~(206)Pb/~(204)b ratios suggesting a more substantial modification of lithospheric source by interaction with asthenosphericderived melts.Cenozoic volcanic rocks of the basanite/tephrite and trachyte/phonolite series define a linear mixing trend between these components,indicating dilution of the initial lithospheric mantle signature by upwelling asthenosphere during rifting.The Pb isotope composition of Late Cretaceous and Cenozoic magmatic rocks of the Bohemian Massif follows the same Pb growth curve as Variscan orogenic lamprophyres and lamproites that formed during the collision between Laurussia,Gondwana,and associated terranes.This implies that the crustal Pb signature in the post-Variscan mantle is repeatedly sampled by younger anorogenic melts.Most Cenozoic mantle-derived rocks of Central Europe show similar Pb isotope ranges as the Bohemian Massif.  相似文献   
17.
随着分析技术的进步,非传统稳定同位素体系在地球化学、天体化学和生物地球化学等研究领域的应用日益广泛。钛(Ti)是一个非常重要的过渡族金属元素,在地球和其他类地球行星中广泛存在。但是由于Ti是一种难熔的、流体不活动性元素,高温地质过程中Ti同位素分馏很小。人们对Ti同位素体系的地球化学应用的关注相对其他非传统稳定同位非常有限。而近年来,随着化学纯化方案的优化以及双稀释剂方法的改进和仪器质谱性能的提高,Ti同位素组成的高精度测试已经能够实现。天然样品中Ti同位素组成的变化随之得以发现,使得学者们能够利用这一新的稳定同位素体系来解决与高温和低温地球化学相关的问题。很快Ti同位素体系地球化学研究成为当前国际地质学界的前沿研究课题和新的发展方向之一。本文首先在简要介绍Ti元素和Ti同位素体地球化学性质的基础上,介绍了Ti元素化学分离和Ti同位素分析方法。随后笔者总结了已有的不同类型球粒陨石和地球样品的质量相关Ti同位素组成研究结果,对硅酸盐地球的Ti同位素组成做了初步评估。前人对高温地质样品的Ti同位素组成研究初步探明Ti同位素在岩浆演化过程,例如部分熔融和结晶分异等重要地质过程中的分馏行为。笔者在此基础上探讨了结晶分异过程中引起Ti同位素分馏的主要控制因素,指出Ti同位素是潜在的研究岩浆演化过程的新工具。最后笔者探讨了Ti同位素地球化学未来的发展方向,以加速我国在Ti同位素地球化学方面的应用研究。  相似文献   
18.
The Lower Silurian Longmaxi Formation in the south of Sichuan is a key player in the exploration and development of shale gas in China. Due to a highly complex topographic area, electromagnetic methods (EM) become important exploration means in this area. Many studies have been conducted on the shale mineral composition and electrical properties of shale, however, the correlation between sedimentary environments and the electrical properties of shale remain poorly understood. The electrical properties and sedimentary environment of the organic-rich shale of the Longmaxi Formation have been studied by means of X-ray diffraction, organic geochemistry, scanning electron microscopy and complex resistivity measurements. The discovered high quartz content of the Longmaxi Formation shale results in low resistivity. Deep-water shelf biogenic quartz contributes lower resistivity more than that of shallow-water terrigenous quartz. The deep-water anoxic and organic sedimentary environment led to major enrichment of pyrite, leading to a high polarization effect in shale. We present the correlation between the lithofacies types and electrical properties of Longmaxi Formation. The mixed siliceous shale lithofacies is the most favorable among the three lithofacies, which is characterized by high total organic carbon (TOC) content, high brittleness mineral content, high polarization and low resistivity (“three high and one low”). This feature is an effective identification of shale gas reservoirs by electromagnetic prospecting. Our study can provide constraints on electrical parameters of rocks for electromagnetic “sweet spot” exploration of shale gas, and so this has important geological significance to shale gas exploration and development.  相似文献   
19.
岩溶含水层的极不均一性特征使岩溶水溶质运移受构造、裂隙空间及其发育方向控制;因环境条件复杂,开展岩溶水污染原位修复技术难度较大,截止目前,国内尚未系统地开展岩溶含水层水污染原位修复研究工作。文章选择鲁中南山区典型岩溶发育及硝酸盐污染地段,施工组合钻孔建设修复试验工程,采用“乙醇+葡萄糖”液态碳源和“聚乙烯醇+淀粉颗粒”固态反应器分别进行岩溶水硝酸盐污染原位修复试验。结果表明:浓度500 mg?L-1、1 000 mg?L-1的“乙醇+葡萄糖”反硝化溶液对硝酸盐浓度的降解率分别为6.45 %和21.52 %;单位长度组成材料“聚乙烯醇3 kg+淀粉颗粒3 kg”、“聚乙烯醇2 kg+淀粉颗粒4 kg”的两种反硝化固态反应器对硝酸盐浓度的降解率分为33.91%和34.96%。试验证明在裂隙型岩溶地区采用孔组方案进行地下水污染原位修复技术可行、且能取得较显著效果。修复工程布设方式和试验成果对类似地区开展岩溶地下水污染原位修复具一定借鉴意义。   相似文献   
20.
王昆  李伟强  李石磊 《地学前缘》2020,27(3):104-122
钾稳定同位素是重要的非传统稳定同位素体系,也是近年来迅速发展的热门研究课题。对钾同位素研究历史和现状进行综述,具体包括以下内容:(1)总结了钾元素的地球化学和宇宙化学性质,包括钾在主要地质储库(地幔、地壳、海洋)中的丰度及其分配,钾在岩浆演化中的不相容大离子亲石性,常见含钾火成岩/沉积岩矿物以及钾在表生过程中的循环,也包括主要行星物质(球粒陨石、非球粒陨石、火星和灶神星陨石以及月球样品)中钾的含量、赋存状态、主要矿物,钾在太阳星云冷凝、行星积聚以及岩浆海过程中的中等挥发性质;(2)介绍了钾同位素的研究历史,从1922年Dempster利用最早的质谱仪测量钾同位素在自然界的丰度,到Taylor和Urey在1938发表的经典的钾同位素分馏实验,再到Humayun和Clayton在1995年发表的钾同位素领域的经典研究,最后到近几年的进展;(3)介绍了对钾的前处理(离子交换柱法)以及钾同位素的主要测量方法,包括早期热电离质谱仪法(TIMS),二次离子质谱仪法(SIMS)和近十几年以来高速发展的多接收电感耦合等离子体质谱仪法(MC-ICP-MS)及其不同的技术路线;(4)介绍了高精度钾同位素比值在低温地球化学和生物地球化学中的应用,包括钾同位素在地表的风化过程中、海水洋壳的反向风化作用中的分馏及其在示踪全球钾元素循环和洋壳俯冲等过程中的应用;(5)介绍了高精度钾同位素比值在高温地球化学中的应用,包括钾同位素在岩浆分异和矿物结晶过程中的分馏;(6)介绍了高精度钾同位素比值在宇宙化学中的应用,包括在太阳星云冷凝、行星凝聚、月球形成大碰撞、岩浆海、火山喷发去气过程中的分馏作用。  相似文献   
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